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[Note: as discussed later pheomelanin may have an additional redox activity, between 0.2 V and +0.25 V.] It is important to note that the observed electrochemical response characteristics indicate that both synthetic melanins are redox-active

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Thus, the discovery positions GGCT as a promising therapeutic target for disrupting metabolic plasticity through its dual roles in Gln shunting and Glc compensation

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On the other hand, iron-triggered lipid peroxidation activates matrix metalloproteinase-9 (MMP-9), which degrades key tight junction proteins such as ZO-1 and occludin, thereby disrupting endothelial barrier structure and increasing vascular permeability (Kim et al., 2022)